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RSC Advances
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                                                                                                                                            Hydrothermal synthesis of flower-like
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                                                                                                                                            molybdenum disulfide microspheres and their
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                                                                                                  Cite this: RSC Adv., 2018, 8, 38945
                                                                                                                                            application in electrochemical supercapacitors
                                                                                                                                            Fangping Wang, * Guifang Li, Jinfeng Zheng, Jing Ma, Caixia Yang
                                                                                                                                            and Qizhao Wang

                                                                                                                                            Three-dimensional flower-like molybdenum disulfide microspheres composed of nanosheets were
                                                                                                                                            prepared by a hydrothermal method using ammonium molybdate as the molybdenum source and
                                                                                                                                            thiourea as the sulfur source. Structural and morphological characterizations were performed by X-ray
                                                                                                                                            diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-
                                                                                                                                            dispersive X-ray (EDX) spectroscopy and X-ray photoelectron spectroscopy (XPS). The electrochemical
                                                                                                                                            properties of MoS2 electrode were studied by performing cyclic voltammetry (CV), galvanostatic charge–
                                                                                                                                            discharge analysis and electrochemical impedance spectroscopy (EIS). When used as an electrode
                                                                                                                                            material for supercapacitor, the hybrid MoS2 showed a high specific capacity of 518.7 F g?1 at a current
                                                                                                                                            density of 1 A g?1 and 275 F g?1 at a high discharge current density of 10 A g?1. In addition, a symmetric
                                                                                                                                            supercapacitor composed of MoS2 as positive and negative electrodes was prepared, which exhibited
                                                                                                  Received 22nd May 2018
                                                                                                  Accepted 31st July 2018
                                                                                                                                            a high energy density of 12.46 W h kg?1 at a power density of 70 W kg?1 and still maintains an impressive
                                                                                                                                            energy density of 6.42 W h kg?1 at a large power density of 7000 W kg?1. The outstanding performance
                                                                                                  DOI: 10.1039/c8ra04350g
                                                                                                                                            of the MoS2 electrode material indicates its great potential for applications in high-performance energy
                                                                                                  rsc.li/rsc-advances                       storage systems.


                                                                                                                                                                                       interest among researchers. At present, carbon materials (such
                                                                                                  1. Introduction                                                                      as activated carbon), transition metal oxides (nickel oxide, etc.),
                                                                                                  Supercapacitors, also known as electrochemical capacitors,                           and conductive polymers are oen used as electrode materials
                                                                                                  have gathered growing interest of researchers in the era of                          for supercapacitors.12,13 However, the growing demand for
                                                                                                  miniaturization of devices.1,2 These present fascinating prop-                       energy storage devices has prompted researchers to develop
                                                                                                  erties of higher energy density, higher power density, longer life,                  new types of electrode materials. Therefore, the research of
                                                                                                  lower toxicity than batteries, and so on, compared with those of                     nanometer-scale metal sulde as the material of supercapacitor
                                                                                                  traditional capacitors.3–6 According to the charge–discharge                         electrode has become a new eld. For example, cobalt sulde
                                                                                                  mechanisms, SCs can be divided into electrical double-layer                          (CoS, CoS2), nickel sulde (NiS, NiS2, Ni3S2), molybdenum
                                                                                                  capacitors (EDLCs) and pseudocapacitors.7,8 Pseudocapaci-                            sulde (MoS2), copper sulde (CuS, Cu2S), and vanadium
                                                                                                  tance arises from reversible faradaic reactions of redox active                      sulde (VS, VS2) have been used as supercapacitors electrode
                                                                                                  materials, such as transition metal oxides, hydroxides, and                          materials.14–16 In particular, MoS2 has aroused interest among
                                                                                                  suldes. Among those materials, ruthenium oxide (RuO2) has                           other transition metal suldes due to its layered structure and
                                                                                                  exhibited excellent pseudocapacitive performance, but the                            inherent conductivity,17 and it is considered to be a suitable
                                                                                                  toxicity and high cost of RuO2 restrict its widespread commer-                       replacement for graphene and carbon nanotubes in energy
                                                                                                  cial application.9,10 The low cost active material MnO2 can also                     storage applications. In addition, molybdenum-based materials
                                                                                                  achieve a high specic capacitance; however, MnO2-based                              (such as MoO3, MoO2, and MoS2) exhibit various valences and
                                                                                                  pseudocapacitors suffer from poor electrical conductivity and                         rich chemical properties, making them viable candidate mate-
                                                                                                  cyclic stability.11 Application of nanometal suldes in the energy                   rials for electrochemical applications.18
                                                                                                  storage devices, such as fuel cells, solar energy pools, lithium-                        MoS2 is a transition metal sulde with a layered structure,
                                                                                                  ion batteries, and supercapacitors, have aroused widespread                          where a metal molybdenum layer is sandwiched between two
                                                                                                                                                                                       sulfur layers; the layers are connected by weak van der Waals
                                                                                                                                                                                       forces and the interlayer S–Mo–S atoms are strongly covalently
                                                                                                  Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education
                                                                                                                                                                                       linked.19–21 MoS2 possesses unique physicochemical properties
                                                                                                  of China, Key Laboratory of Gansu Polymer Materials, College of Chemistry and
                                                                                                  Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.
                                                                                                                                                                                       due to its unique atomic and electronic structure. It is mainly
                                                                                                  E-mail: wangfp@nwnu.edu.cn                                                           used in the solid lubricants, catalysts, supercapacitors and


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                                                                                                  lithium-ion batteries.22–24 Among these, the research on the            and heated at 200 ? C for different time periods (8 h, 16 h, and 24
                                                                                                  application of MoS2 as a supercapacitor electrode material is the       h). The obtained MoS2 was ushed with water and ethanol, in
                                                                                                  most extensive. For example, Soon et al.25 found that the MoS2          sequence, and then dried at 70 ? C for 12 h. The MoS2 electrode
                                                                                                  nano-lm presented an electric double layer capacitance                 materials were denoted as MoS2-8, MoS2-16, and MoS2-24,
                                                                                                  behavior. Ma et al.26 reported that nano-MoS2 intercalated in           according to the hydrothermal treatment time.
                                                                                                  polypyrrole could improve its capacitance performance. Cao
                                                                                                  et al.27 fabricated micro-supercapacitors using coated MoS2
                                                                                                                                                                          2.3. Material characterization
                                                                                                  nanolms, and showed that MoS2 has excellent electrochemical
                                                                                                  performance in aqueous electrolytes.                                    The morphology and microstructure of the samples were
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                                                                                                      In particular, the structure of the electrode directly affects its   characterized by eld-emission scanning electron microscopy
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                                                                                                  electrochemical properties. Generally, the electrochemical              (FESEM JSM-6701F, Japan), transmission electron microscopy
                                                                                                  electrode is 2-dimensional and suffers from inadequate contact           (TEM; JEOL, JEM-2010, Japan), and X-ray diffraction (XRD, D/
                                                                                                  with electrolyte and low surface-area-utilization efficiency.             Max-2400, Japan) with Cu Ka radiation (l ¼ 1.5418 Å) oper-
                                                                                                  Numerous efforts have been made to design three-dimensional              ating at 40 kV, 100 mA. X-ray photoelectron spectroscopy (XPS)
                                                                                                  (3D) electrodes, such as MoS2/mesoporous carbon spheres.                spectra were recorded on a PHI 5702 spectrometer using
                                                                                                  Recently, there have been some reports related to NiCo2S4 and           a standard Al Ka X-ray source of 300 W and an analyser pass
                                                                                                  graphene oxide composites applied in supercapacitors. Krish-            energy of 29.35 eV.
                                                                                                  namoorthy et al.15 reported 92.85 F g?1 specic capacitance of
                                                                                                  chemically prepared MoS2 nanostructure. Huang et al.28 re-              2.4. Electrode preparation and electrochemical
                                                                                                  ported polyaniline/MoS2 composites as supercapacitor elec-              characterization
                                                                                                  trodes with the specic capacitance of 575 F g?1.
                                                                                                      In this paper, the morphologically regular ower-like               The electrochemical properties of the MoS2 nanostructures
                                                                                                  molybdenum disulde microspheres were successfully synthe-              were investigated in 1 M Na2SO4 solution using a three-
                                                                                                  sized by a hydrothermal method (Fig. 1). The as-prepared MoS2           electrode system in an electrochemical work station
                                                                                                  was directly used as a supercapacitor electrode and exhibited           (CHI660E, Shanghai). Initially, 8 mg of MoS2-16 was dispersed
                                                                                                  high specic capacitance (518.7 F g?1 at current density of             in 400 mL of 0.5 wt% Naon solution by ultrasonication to
                                                                                                  1 A g?1) and excellent cycling performance (88.2% retention             obtain a well dispersed suspension. Then, 6 mL of the suspen-
                                                                                                  aer 2500 cycles). In addition, a high performance symmetric            sion was drop-casted onto the pre-treated glassy carbon elec-
                                                                                                  supercapacitor was successfully fabricated by using MoS2 as             trode (GCE) and le to dry at room temperature. Saturated
                                                                                                  both positive electrode and negative electrode, which exhibited         calomel electrode, platinum wire, and a loadable glassy carbon
                                                                                                  a high energy density of 12.46 W h kg?1 at power density of             electrode were respectively the reference, the counter, and the
                                                                                                  70 W kg?1.                                                              working electrodes.29 Cyclic voltammetry (CV) in the range ?0.3
                                                                                                                                                                          to 0.5 V was performed at different scan rates. Galvanostatic
                                                                                                                                                                          charge–discharge curves were recorded in the potential range of
                                                                                                  2.       Experimental section                                           ?0.3 to 0.5 V at different constant current density. The cycle life
                                                                                                  2.1. Materials                                                          tests were performed by galvanostatic charge–discharge
                                                                                                                                                                          measurements with a constant current density of 4 A g?1 for
                                                                                                  Ammonium molybdate ((NH4)6Mo7O24$4H2O) and thiourea
                                                                                                                                                                          2500 cycles. Electrochemical impedance spectroscopy (EIS) was
                                                                                                  (CH4N2S) were obtained from Tianjin Kaixin Chemical Industry
                                                                                                                                                                          performed in the frequency range of 0.01 Hz to 100 kHz with
                                                                                                  Co. Ltd. All the chemical reagents were of analytical purity and
                                                                                                                                                                          5 mV amplitude at current open circuit voltage.
                                                                                                  used without any further purication.
                                                                                                                                                                             A two-electrode symmetric supercapacitor cell was assem-
                                                                                                                                                                          bled to measure the device performances. MoS2 was used as the
                                                                                                  2.2. Synthesis of MoS2                                                  positive electrode and negative electrode. The negative elec-
                                                                                                  In a typical process, 0.8 g of ammonium molybdate and 5.12 g            trode was prepared by the traditional slurry coating method.
                                                                                                  thiourea were dissolved into 80 mL deionized water and stirred          The mass loading of electroactive material in symmetric
                                                                                                  until the solution was clear and transparent. The solution was          supercapacitor was 0.3 mg. The specic capacitances (Cm) were
                                                                                                  transferred into 100 mL PTFE-lined stainless steel autoclave            calculated according to the following equations:30–32




                                                                                                  Fig. 1   Schematic of the MoS2 synthesized by hydrothermal method.



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                                                                                                                                        I ? Dt                         403 cm?1, related to the characteristic vibrations of pure
                                                                                                                               Cm ¼                              (1)
                                                                                                                                       m ? DV                          metallic phase MoS2. The main peak associated with Mo–Mo
                                                                                                                                                                       metallic vibration is located at 145 cm?1. Two characteristic
                                                                                                  where Cm is the specic capacitance, I is the current of the
                                                                                                                                                                       peaks are observed at 371 and 403 cm?1, which correspond to
                                                                                                  charge–discharge, Dt (s) is the discharge time, DV is the voltage
                                                                                                                                                                       the E2g1 and Ag1 modes of hexagonal MoS2, and are attributed to
                                                                                                  window, and m is the mass of active materials.
                                                                                                                                                                       the out-of-plane Mo–S phonon mode and the in-plane Mo–S
                                                                                                     In the symmetrical supercapacitors, the corresponding
                                                                                                  power density (P) and energy density (E) were calculated             phonon mode, respectively.
                                                                                                  according to the following equations.8                                  The chemical and surface states of the Mo and S elements in
                                                                                                                                                                       the as-prepared MoS2-16 electrodes have been investigated via
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                                                                                                                                     Cm ? DV 2                         X-ray photoelectron spectroscopy. The XPS survey spectrum of
                                                                                                                              E¼
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                                                                                                                                                                 (2)
                                                                                                                                         2                             the MoS2 electrodes is shown in Fig. 5a, which revealed the
                                                                                                                                                                       presence of Mo 3d, Mo 3p, S 2p, C 1s and O 1s states.33 The C
                                                                                                                                         E
                                                                                                                                   P¼                            (3)   and O signals originated from the CO2 and H2O impurities, as
                                                                                                                                         Dt
                                                                                                                                                                       seen in many XPS analyses. The ne tted spectrum of Mo 3d is
                                                                                                                                                                       shown in Fig. 5b, which revealed the presence of two major
                                                                                                                                                                       peaks at around 228.5 and 232 eV, corresponding to the Mo4+
                                                                                                  3.      Results and discussion                                       3d5/2 and Mo4+ 3d3/2 states, respectively. Small peaks belonging
                                                                                                                                                                       to S 2s in the vicinity of 226 eV are also observed.34 The ne
                                                                                                  3.1. Characterization of MoS2                                        tted spectrum of S 2p (Fig. 5c) indicated the presence of two
                                                                                                  Fig. 2 shows the SEM microstructures of the as-prepared MoS2-        major peaks at around 161.5 and 162.9 eV, which corresponds
                                                                                                  8, MoS2-16, and MoS2-24. It can be clearly observed from the         to the S 2p3/2 and S 2p1/2 states, respectively.35 These studies
                                                                                                  Fig. 2 that the as-prepared molybdenum disulde material has         conrm the formation of MoS2 by the hydrothermal method.
                                                                                                  a nanoower-like structure assembled from clear nanoakes.
                                                                                                  Different hydrothermal treatment times had a great inuence
                                                                                                  on the size of the molybdenum disulde nanoakes and the             3.2. Electrochemical and energy storage performance
                                                                                                  size of the three-dimensional pore structure. Fig. 2a and b show     Fig. 6a shows the cyclic voltammetry (CV) curves of MoS2-8,
                                                                                                  the SEM microstructures of the MoS2-8 at low and high                MoS2-16 and MoS2-24 at 10 mV s?1 in 1 M Na2SO4 solution,
                                                                                                  magnications, respectively. It can be seen that the nanosheets      obtained over the potential range between ?0.3 V and 0.5 V. In
                                                                                                  are partially adhered together and contained a small amount of       contrast, the CV curve area of the MoS2-16 electrode was larger
                                                                                                  block-like structures, resulting in inconspicuous pore structure.    than the electrode area of MoS2-8 and MoS2-24. Fig. 6b shows
                                                                                                  MoS2-16 (Fig. 2c and d) possesses an evenly distributed larger       the cyclic voltammetry (CV) curves of MoS2-16 at different scan
                                                                                                  size of nanoakes, and forms highly open and relatively deep         rates. On increasing the scanning speed from 10 mV s?1 to
                                                                                                  porous nanostructures, making optimal use of the grain surface       100 mV s?1, the shape of the CV curve did not change signi-
                                                                                                  readily accessible to the liquid electrolyte and providing effi-       cantly, indicating that MoS2-16 presented better rate perfor-
                                                                                                  cient channels for electron transport. Fig. 2e and f present the     mance and small polarization.36,37 Galvanostatic charging–
                                                                                                  low and high magnication SEM image of the MoS2-24 sample.           discharging (GCD) technique was also applied to study the
                                                                                                  Aer a 24 h long hydrothermal process, the nanosheets of MoS2-       electrochemical capacitive properties of MoS2-8, MoS2-16 and
                                                                                                  24 arranged regularly but too tightly, and some collapsed,           MoS2-24 at a current density of 1 A g?1, as shown in Fig. 6c. The
                                                                                                  resulting in a decrease or disappearance of the pore size in the     longer discharge time of MoS2-16 electrode again conrmed its
                                                                                                  material, which could degrade the electrochemical performance        enhanced capacitance. Fig. 6d shows the galvanostatic charge–
                                                                                                  of the electrode material.                                           discharge curve (GCD) of MoS2-16 at various current densities
                                                                                                     Fig. 3 shows the TEM images for MoS2-16. As shown in              varying from 1 to 10 A g?1, with a potential window range from
                                                                                                  Fig. 3a, the interconnected nanoakes consist of nano-owers.        ?0.3 V to 0.5 V. Based on eqn (2), for MoS2-16 electrode, at
                                                                                                  As seen in the magnied image (Fig. 3b), MoS2-16 nanoakes           a discharge current of 1 A g?1, the specic capacitance reached
                                                                                                  are very thin, leading to open and porous three-dimensional          518.7 F g?1, while at a high discharge current of 10 A g?1, the
                                                                                                  structures, which are benecial to electrolyte access and elec-      specic capacitance was as high as 275 F g?1. Using these GCD
                                                                                                  tron transport during electrochemical reactions. These results       curves, the specic capacitances of ve electrodes at various
                                                                                                  are in accordance with the SEM images.                               current densities were calculated and depicted in Fig. 6e. The
                                                                                                     The XRD patterns of MoS2-8, MoS2-16, and MoS2-24 hybrids          calculated specic capacitances of MoS2-16 electrode were
                                                                                                  are shown in Fig. 4a. The four diffraction peaks at 14.2? , 32.5? ,   calculated to be 518.7, 415, 363.7, 335, 318.7, and 275 F g?1 at
                                                                                                  35.8? , and 55.4? correspond to the (002), (100), (102) and (106)    discharge current densities of 1, 2, 3, 4, 5, and 10 A g?1,
                                                                                                  planes of cubic phase MoS2 (JCPDS No. 75-1539). Energy-              respectively, which are much higher than those for MoS2-8 and
                                                                                                  dispersive X-ray (EDX) spectroscopy (Fig. 4b) demonstrates the       MoS2-24 at the same current densities. Table 1 compares the
                                                                                                  existence of Mo and S elements. The Raman spectrum of the as-        electrochemical performance of the MoS2 electrode material
                                                                                                  prepared MoS2 nanoowers was recorded in this study, as              prepared in this study with that of the MoS2 electrode material
                                                                                                  shown in Fig. 4c. At low wave numbers the Raman spectrum of          reported in the literature. It can be seen that the electro-
                                                                                                  the MoS2 sample showed peaks at 145, 227, 283, 371 and               chemical performance of the MoS2 electrode material prepared


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                                                                                                  Fig. 2   SEM images of (a and b) MoS2-8, (c and d) MoS2-16, and (e and f) MoS2-24.




                                                                                                  Fig. 3   TEM images of MoS2-16.




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                                                                                                  Fig. 4 (a) XRD pattern of the MoS2-8, MoS2-16, and MoS2-24; (b) EDX spectra of MoS2-16; (c) Raman spectra of MoS2-16.



                                                                                                  in this experiment is superior. The superior electrochemical             resistance. Nyquist plots based on the radius of the high
                                                                                                  behaviors of MoS2-16 nanoower observed in this study should             frequency arc on the real axis are shown in Fig. 6f. Clearly, the
                                                                                                  be partially attributed to its ultrathin and porous features,            semicircle over the high frequency range of the MoS2-16 elec-
                                                                                                  which can offer even richer electroactive sites, and more effi-             trode is smaller than that of others, indicating the smaller
                                                                                                  cient and convenient electronic transport.                               charge-transfer resistance. Furthermore, the slope of the line
                                                                                                     Electrochemical impedance spectroscopy (EIS) analysis is              for MoS2-16 was larger than that of MoS2-8 and MoS2-24,
                                                                                                  an important tool to examine the interface resistance of elec-           implying a better capacitive behavior and a lower diffusion
                                                                                                  trode materials for supercapacitors. For an ideal super-                 resistance of ions in the MoS2-16 electrode material. The
                                                                                                  capacitor, the Nyquist plot comprises a vertical line, which can         differences in the electrochemical properties of MoS2 material
                                                                                                  be simulated by an equivalent circuit. The semicircle at high            are mainly due to disparity in the material electrolyte interface
                                                                                                  frequency region is indicative of interfacial charge transfer            properties and electrolyte ion diffusion rates during the
                                                                                                  resistance. In the equivalent circuit, the series resistance (R)         charge–discharge processes, which are in good accordance
                                                                                                  depends on electrolyte resistance and electrode electronic               with its abovementioned electrochemical performance.




                                                                                                  Fig. 5   (a) XPS survey scanning of MoS2-16. XPS spectra of (b) Mo 3d and (c) S 2p.



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                                                                                                  Fig. 6 (a) Cyclic voltammograms of MoS2-8, MoS2-16, and MoS2-24 at 10 mV s?1. (b) CV curves of the MoS2-16 electrode at different scan rates. (c)
                                                                                                  Galvanostatic discharge curves of MoS2-8, MoS2-16 and MoS2-24 at a current density of 1 A g?1. (d) GCD curves of MoS2-16 at various current
                                                                                                  densities. (e) Specific capacitance as a function of the current density of the MoS2-8, MoS2-16, and MoS2-24. (f) Nyquist plots of MoS2-8, MoS2-16,
                                                                                                  and MoS2-24 electrodes in the frequency range from 100 kHz to 0.01 Hz. (g) Cycle performance for the MoS2-16 electrodes at a current of 4 A g?1.


                                                                                                     The cyclic stability of the electrode material is very                 current density of 4 A g?1 (Fig. 6g). Although the specic
                                                                                                  important for practical supercapacitor applications. The                  capacitance gradually decreases with the increase of cycle
                                                                                                  cycling performance of MoS2-16 electrode was tested by 2500               number, there is still 88.2% retention of the initial
                                                                                                  cycles of continuous galvanostatic charge/discharge at the                capacitance.


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                                                                                                  Table 1   Comparison of electrochemical properties of different MoS2 electrode materials

                                                                                                  Samples                                     Electrolyte           Current density               Specic capacitance                References

                                                                                                  MoS2 nanosheets                             1 M Na2SO4            1 A g?1                       129.2 F g?1                        38
                                                                                                  Sphere like MoS2                            1 M Na2SO4            5 mV s?1                      106 F g?1                          39
                                                                                                  Spherically clustered MoS2                  1 M H2SO4             5 mV s?1                      113 F g?1                          40
                                                                                                  MoS2 nanospheres                            1 M KCl               1 A g?1                       122 F g?1                          41
                                                                                                  Hollow MoS2 nanospheres                     1 M KCl               0.59 A g?1                    144 F g?1                          42
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                                                                                                  MoS2 monolayers                             6 M KOH               0.5 A g?1                     366.9 F g?1                        43
                                                                                                                                                                    0.5 A g?1                     268 F g?1
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                                                                                                  MoS2/CMG                                    1 M Na2SO4                                                                             44
                                                                                                  MoS2/MWCNT                                  1 M Na2SO4            1 A g?1                       452.7 F g?1                        45
                                                                                                  MoS2-16                                     1 M Na2SO4            1 A g?1                       518.7 F g?1                        This work




                                                                                                  Fig. 7 (a) CV curves of MoS2-16//MoS2-16 measured at different potential windows at a scan rate of 30 mV s?1. (b) CV curves of the SC measured
                                                                                                  at different scan rates ranging from 20 to 120 mV s?1 in potential window of 0 to 1.6 V. (c) Galvanostatic charge/discharge curves of the SC
                                                                                                  measure at different current densities from 1 to 10 A g?1. (d) Specific capacitance as a function of the current density of the symmetric
                                                                                                  supercapacitor. (e) Ragone plots of the SC. (f) Cycling stability of the SC at 1.6 A g?1.



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                                                                                                  3.3. Electrochemical performances of the MoS2-16//MoS2-16             supercapacitor was assembled using the MoS2-16 nanoower as
                                                                                                  symmetric supercapacitor                                              both positive electrode and negative electrode. This super-
                                                                                                                                                                        capacitor delivered a maximum energy density of
                                                                                                  To further evaluate the practical application potential of MoS2-
                                                                                                                                                                        12.46 W h kg?1 at a power density of 70 W kg?1. Even at the
                                                                                                  16 electrode, an aqueous SC was rst assembled using the
                                                                                                                                                                        highest power density of 7000 W kg?1, the MoS2-16//MoS2-16
                                                                                                  MoS2-16 electrode as both positive electrode and negative
                                                                                                                                                                        device still maintained an energy density of 6.42 W h kg?1. Such
                                                                                                  electrode. Fig. 7a shows a series of CV curves collected at 30 mV
                                                                                                                                                                        outstanding capacitive behaviors imply the MoS2-16 nanoower
                                                                                                  s?1 with an operating SC voltage ranging from 0.8 to 1.6 V to
                                                                                                  obtain the best operating potential of MoS2-16//MoS2-16. Fig. 7b      as a promising material for energy storage devices.
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                                                                                                  shows typical CV curves for the SC device corresponding to
Open Access Article. Published on 19 November 2018. Downloaded on 1/19/2026 4:49:56 PM.




                                                                                                  different sweep rates. With the increment of sweep rate from 20        Conflicts of interest
                                                                                                  to 120 mV s?1, all the curves presented similar shapes, revealing
                                                                                                  the splendid high-rate charge–discharge performance of the            There are no conicts to declare.
                                                                                                  device.46–48 Fig. 7c shows the typical GCD curves of the cells at
                                                                                                  various current densities with a potential window of 0–1.4 V.
                                                                                                  During the charge and discharge processes, the charge curve of
                                                                                                                                                                        Acknowledgements
                                                                                                  MoS2-16//MoS2-16 (SSC) and its corresponding discharge curve          We gratefully acknowledge the nancial support of this
                                                                                                  are observed to be symmetrical, conrming that it has excellent       research by the National Natural Science Foundation of China
                                                                                                  electrochemical reversibility.49 The calculated specic capaci-       (21065010, 21365019).
                                                                                                  tance values based on the discharge curves are plotted in
                                                                                                  Fig. 7d, which are 45.7, 43.7, 42.8, 42.3, 39.8, 36.9 and 23.57 F
                                                                                                  g?1 at 0.1, 0.2, 0.3, 0.4, 1, 2, and 10 A g?1, respectively. Energy   References
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                                                                                                  38952 | RSC Adv., 2018, 8, 38945–38954                                                    This journal is © The Royal Society of Chemistry 2018

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                                                                                                  38954 | RSC Adv., 2018, 8, 38945–38954                                                This journal is © The Royal Society of Chemistry 2018
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  1. https://rexresearch.com/MoS2Nanoflowers/Hydrothermalc8ra04350g.pdf

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Source illustrations for MoS₂ nanoflowers. Captions identify the document and evidence type.

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Thematic connections, not evidence of a shared mechanism